Highly-oxidised, sulfur-rich, mixed-valence vanadium(iv/v) complexes Academic Article uri icon

abstract

  • The reactions of [V(2)(micro-S(2))(2)(S(2)CNR(2))(4)] (R = alkyl) with NOBF(4) produce highly-oxidised, sulfur-rich, V(iv/v) complexes, [V(2)(micro-S(2))(2)(S(2)CNR(2))(4)]BF(4), that exhibit 15-line EPR spectra and structures consistent with Class III mixed-valence behaviour.

publication date

  • 2006